Conventional twostep reforming topsoes conventional technology for producing syngas in methanol plants involves the socalled two step reforming concept 1 fig. This might mitigate the distribution problems associated with hydrogen. A study of ethanol and methanol as a fuel for onboard hydrogen generation by steam reforming on copperbased. Steam reforming of methanol is endothermic overall i. The basic idea is that for example a methanol tank and a steam reforming unit would replace the bulky pressurized hydrogen tanks that would otherwise be necessary. The main purpose of this technology is to hydrogen production. This chapter focuses mainly on the challenges of catalyst development for methanol steam reforming. Cuznoal2o3 catalysts have been prepared via hydrotalcitelike hydroxycarbonate precursors and tested in the oxidative steam reforming of methanol mosr to produce hydrogen with poor co content. Methanol steam reforming for fuel cell applications. Pdf methanol steam reforming for hydrogen production. In methanol synthesis involving modern promoted cuznoal2 o3 catalysts neither poisoning nor coking is normally a significant source of deactivation.
Compact unit in combining both reaction and hydrogen purification with a. A potential advantage of the membrane microreactor is the fact that both ethanol steam reforming and the separation of hydrogen by a permselective membrane occur in one single microdevice. The primary ways in which methane, is converted to hydrogen. Generally methanol reforming reaction occurs at comparatively lower temperature 200300c as compared to the temperature 800900c for gasoline reforming. The wellknown steam reforming process usually used to extract hydrogen from methanol, called the methanol reformer, traditionally produces carbon.
Steam reforming is the most efficient and popular way of producing hydrogen gas. Methanol steam reforming for in situ hydrogen production for fuel cell applications has been studied mostly as a standalone process. Pdf modeling methanol steam reforming for internal. Atr combines substoichiometric combustion and catalytic steam reforming in one compact refractory lined reactor to produce synthesis gas for production of more than 10,000 mtpd of methanol. An efficient technique for improving methanol yield using dual co 2. Pdf in the recent years, hydrogen has gained a considerable interest as an energy. The reaction yields carbon dioxide and hydrogen in the ratio of one to three, with small amounts of dimethyl. Using 23wt% cu80zno20cnts as the catalyst, we obtained the hydrogen yield for steam reforming of methanol of 83% at 280c and near 100% at temperatures higher than 320c with 1. The reaction is very endothermic and typically occurs in a fixed bed reactor, heated by an open flame furnace with natural gas as the feedstock. Methanol steam reforming for hydrogen production chemical. Review article covering developments in methanol steam reforming in the context of pem fuel cell power systems. Over cuzno catalysts prepared by a coprecipitation method, the steam reforming of methanol occurs with high selectivity regardless of composition of the catalyst and structure of the precursor aurichalcite, malachite, hydrozincite or their mixture. A methanol reformer is a device used in chemical engineering, especially in the area of fuel cell technology, which can produce pure hydrogen gas and carbon dioxide by reacting a methanol and water steam mixture.
Jul 30, 20 methanol reformers are large largest reformer has 960 tubes two to three times the size of an ammonia reformer many reformers in the range 600900 tubes why is this. Methanol is considered an attractive raw material due to the high hydrogencarbon ratio 4. Mar 21, 2012 methanol might thus play a key role in the transition toward a future energy scenario, which has to be more and more independent from fossil sources. For a comparison, the catalytic performance of sm support was also measured. Aug 07, 1990 the production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800 to about 1,100 f. Nonsyngas direct steam reforming of methanol to hydrogen and. Methanol steam reforming for hydrogen generation via. Steam reforming of liquid hydrocarbons is seen as a potential way to provide fuel for fuel cells. Deactivation of copper metal catalysts for methanol. The simulation results for steam reforming yields are in agreement with experimental data found in the literature. Development of a methanol reformer for fuel cell vehicles. All reforming is done in this reformer there is no secondary therefore choose the cheapest design and easiest to scale up therefore use top fired why. Kinetics, catalysis and mechanism of methane steam reforming.
Methanol has a low boiling point, a high hydrogencarbon ratio and no cc bonds, and can therefore be reformed at a relatively low temperature, reducing the risk of coke formation during the reaction. Pdf hydrogen production by the catalytic steam reforming. A nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst. Methanol steam reforming for hydrogen generation via conventional. Pdf methanol steam reforming for hydrogen generation via.
Compact fuel cell type steam methane reformers with concentric annular. A new palladiumbased catalyst for methanol steam reforming in. Methanol steam reforming for hydrogen generation via conventional and membrane. Nov 27, 2012 a nonsyngas direct steam reforming route is investigated for the conversion of methanol to hydrogen and carbon dioxide over a cuzngaox catalyst at 150200 c. In contrast, catalyst poisoning and coking have been observed in methanol decomposition and methanol steam reforming reactions. Classical pemfc stack operates at 90 c while hightemperature pemfc stack operates at 250 c. Nonsyngas direct steam reforming of methanol to hydrogen. Hydrogen production by steam reforming of ethanol over pt. Steam reforming of methanol for fuel cell grade hydrogen. Methanol steam reforming behavior of copper impregnated over ceo 2 zro 2 derived from a surfactant assisted coprecipitation route. Study on coupling model of methanol steam reforming and. An external reformer system consists of a combustor where a small fraction of fuel is burned and provides heat for the following steps, a vaporizer to heat and vaporize the fuel. Methanol steam reforming msr reaction has been seen as a very attractive and.
Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. In both systems the methanol reformer operates at 250 c and steamtomethanol ratio of 1. The top countries of supplier is china, from which the percentage of methanol reforming supply is 95% respectively. Combined steam reforming and partial oxidation of methane to. A wide variety of methanol reforming options are available to you, there are 180 suppliers who sells methanol reforming on, mainly located in asia. The steam reformer how fuel processors work howstuffworks. Proven autothermal reforming technology for modern large. Steam reforming of methane produces a mixture of co2, co, and h2. The steam reforming of methanol over a cuznoal2o3 catalyst has been investigated. Stable hydrogen production from ethanol through steam. Combined steam reforming and partial oxidation of methane to synthesis gas under electrical discharge korada supat and sumaeth chavadej the petroleum and petrochemical college, chulalongkorn university, bangkok 10330, thailand. Review of small stationary reformers for hydrogen production. It also makes the steam reforming process of methanol energetically favorable.
Autothermal reformers atrs combine some of the best features of steam reforming. In the first part of the plant natural gas is converted into synthesis gas. Subjects covered include methanol background, use, and production, comparison to. Jul 28, 20 steam reforming the basics of reforming 1. Hydrogen production by the catalytic steam reforming of methanol part 1.
Methanol steam reforming over exhydrotalcite cuznal. Pdf progress in methanol steam reforming modelling via. Srm is defined as steam reforming of methanol frequently. Methanol steam reforming also requires relatively low water to carbon molar ratio. C2pt catalyst process technology by gerard b hawkins managing director 2. During steam reforming of ethanol, catalyst plays a major role in the productivity and selectivity of generated gas.
Methanol steam reforming in a dual bed membrane reactor for. Methanol steam reformer high temperature pem fuel cell system. Ethanol contains higher number of hydrogen per molecule as compared to water, methanol and methane. Parametric study of hydrogen production from ethanol steam. Mwcnts as a catalyst in oxysteam reforming of methanol. Additionally, the system with a classical pemfc stack uses a catalytic burner to supply the endothermal reforming process with sufficient heat. From a technical point of view methanol is the ideal fuel, as it can easily be converted into hydrogen at reasonable temperatures methanol steam reforming and selective co methanation. Micromachined methanol steam reforming system as a hydrogen.
Study of different designs of methanol steam reformers. Experiment and modeling article pdf available in international journal of hydrogen energy 3935 october 2014 with 379 reads. Final forms of the rate expressions for the overall reactions involved in the process of steam reforming of methanol can be expressed as. Catalytic steam reforming of methanol to produce hydrogen on. Advances in methanol production and utilization, with. The goal of the reformer is to remove as much of the hydrogen h as possible from this molecule, while minimizing the emission of pollutants such as carbon monoxide co.
Methanol steam reforming msr reaction has been seen as a very attractive and promising process for hydrogen production and, according to the scientific literature on the argument, it can be described by the following chemical reactions. Semipassive dmfcs represents a particular class able to combine. The capital cost of large scale methanol plants is substantial. Steam reforming and partial oxidation are the two basic types of fuel. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. In describing methanol steam reforming, we have limited our. There are a couple of types of steam reformers, one reforming methanol and the other reforming natural gas. Chemical reactions catalyst shape design catalyst chemistry carbon formation and removal 3. Steam reforming sr of methanol has been extensively studied in recent years 17. Implementing glycerol steam reforming will make hydrogen production less dependent on finite fossil fuels 32. Steam methane reforming smrbased methanol synthesis plants.
Micromachined methanol steam reforming system as a hydrogen supplier for portable proton exchange membrane fuel cells daeeun parka. Hydrogen production by steam reforming of ethanol over ptceo 2 catalyst in electric field at low temperature. Modeling methanol steam reforming for internal combustion engine. Steam methane reforming is the most common and economical way to make hydrogen. Mechanistic kinetic models for steam reforming of concentrated crude. Dec 25, 2014 steam reforming of ethanol was carried out at 500 c over the ni catalysts prepared, which were compared to the total conversion and h 2 yield at the initial stage after 5 min and at the later stage after 200 min figure 2. Steam reforming of methanol for fuel cell applications. John bogild hansen haldor topsoe methanol workshop, lund university march 17, 2015. The synthesis gas reacts to produce methanol in the second section, and methanol is purified to the desired purity in the tailend of the plant. Method of steam reforming methanol to hydrogen engelhard. At present, most of the worlds hydrogen is produced from natural gas 97 % ch4 by a process called steam reforming 38.
1285 599 633 683 162 926 94 1343 1513 8 861 310 372 832 477 383 1031 1001 943 1511 1417 811 1078 916 966 330 879 457 1139 782 110 179